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17.4.1.4.1.1 Of Hydrogen

DOI: 10.1055/sos-SD-017-00971

von Angerer, S.Science of Synthesis, (200417648.

The bridged annulene 5,10-epoxy[10]annulene (92) behaves as an aromatic 10π-system rather than as an oxepin, and reacts with copper(II) nitrate in acetic anhydride to give a 1:1 mixture of 1-nitro-5,10-epoxy[10]annulene (115) and 2-nitro-5,10-epoxy[10]annulene (116) (Scheme 34).[‌116‌]

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