Navigation

0 Hits

  • Previous / Next

You are using Science Of Synthesis as a Guest.
Please login to access the full content or check if you have access via
17.9.2 Product Subclass 2: Metal–Phthalocyanine Complexes

DOI: 10.1055/sos-SD-017-01835

McKeown, N. B.Science of Synthesis, (2004171247.

Phthalocyanine (1) can act as a ligand to most, if not all, metal and metalloid elements, although complexes with some metals such as the more active actinides have not been reported to date. Phthalocyanine has proved itself a versatile macrocycle, which adapts to the requirements of each metal species (M) to form a complex of an appropriate structure (Scheme 8), sometimes with the involvement of additional ligands (L) (Scheme 9). The normal oxidation state of the phthalocyanine macrocycle is 2. Therefore, if M represents a metal ion with a charge of +2 there is no need for additional ligands to retain neutrality, although neutral ligands such as pyridine or water are often incorporated.

Meeeee 8 Mee Meeeeeeee ee MeeeeMeeeeeeeeeeeee Meeeeeeee

Meeeee 8 Mee Meeeeeeee ee MeeeeMeeeeeeeeeeeee Meeeeeeee Meeee Meeeeee Meeeeeeeee Meeeeee

Me eeeeeeee ee eee eeeeeee eeeeeeeee ee eee eeeeeeeee eeeeeeee, eeeee-eeeeeeeeee eeeeeeeeeeeeeee eeee eeee eeeeeeee eeee eeeeeeeee eeee eee eee eeeeeeeeeeeee eeeeee, eeee ee eee eeee eeeeeeeeeee ee eeeeeee eeeeeeeeeeeeeeeeeee (Meeeeee 88.8.88).[‌888‌] Meeeeeeee(MM) eeeeeeeeeeeeee eee eeee eeeeeeee eeee eeeeeeeeeeeeeeeeeeeee­eeeeeeeeeeee (Meeeeee 88.8.88) ee eeeeeeeeeeeeeee eeee eeeeeeee eeeee.[‌88‌]

References


Cookie-Einstellungen