Science of Synthesis

Schmidt, J.; Silks, L. A., Science of Synthesis, (2005) 18, 981.

The use of carbon diselenide for the construction of cyclic selenocarbamates is a straightforward process. However, a more general use of carbon diselenide is hindered by its propensity to polymerize under a variety of conditions. In addition, the commercial availability is limited. Despite its cost and limited availability, carbon diselenide is operationally easy to use and often simply adding it to a solution with a co-reactant such as 1,2-amino alcohol ‌37‌ and reagent will give rise to the product ‌38‌ as illustrated in ‌Scheme 16‌.[‌53‌,‌54‌]

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References