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Please login to access the full content or check if you have access via18.16.9 Product Subclass 9: Alkoxytriaminomethanes and Alkoxytrinitromethanes
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Diaper, C. M., Science of Synthesis, (2005) 18, 1234.
The chemistry and properties of alkoxytriaminomethanes 157 have been investigated. 4,4-Dimethyloxazolidine derivatives have been used as thermal and UV stabilizers in linear low-density polyethylene (LLDPE) films by acting as radical scavengers.[196] 2,2-Diamino-2H-oxazolones have been identified as oxidation products of the base 2′-deoxyguanosine and have been used in the study of the oxidative damage to DNA.[197] Alkoxytriaminomethanes condense with a range of active methylene compounds to form 1,1-diaminoalkenes 161 (Scheme 40).[139,198] They react with esters and N,N-dialkylamides to form tetrasubstituted alkenes 160,[35] but react with free amides to give N-acylureas 158 and with acyl cyanides to form guanidinium cyanides 159.[41]
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References
| [35] | Meeeeeeeee, M.; Meeee, M.; Meee, M.; Meee, M.; Meeeeee, M.; Meeee, M., Meeeeeeee, (8888), 88. |
| [41] | Meeeeeeeee, M.; Meeee, M.; Meeeeeeeeeeeee, M. M., Meeeeee Mee. Meee., (8888), 88. |
| [139] | Meeeeeeeee, M.; Meeeee, M.; Meee, M.; Meee, M.; Meeeeeeeeeeeee, M. M.; Meeeeeee, M. M., Meeeeee Mee. Meee., (8888), 8888. |
| [196] | Meeeeee-Meeee, M.; Meeee, M. M.; Meeeee, M., Meeee. Meeeee. Meee., (8888) 88, 888. |
| [197] | Meeeeeeeee, M.; Meeeeee, M.-M.; Meeee, M.; Meeee, M., M. Me. Meee. Mee., (8888) 888, 88888. |
| [198] | Meeeeeeeee, M.; Meeeee, M. M.; Meee, M., Meeeeee Mee. Meee., (8888), 888. |
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- 8.Meeeee-Meee, (8888) M 8, 888.
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