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19.6.2.2.1 Variation 1: Addition of Enophiles

DOI: 10.1055/sos-SD-019-00284

Bergsträßer, U.Science of Synthesis, (200419438.

Terminal alkenes, alkylidenecyclopropanes 55, and allenes 57 undergo thermal addition to phosphaalkynes via tandem ene reactions to give the corresponding alkyl-substituted phosphines 56 and 58, respectively (Scheme 19).[‌5‌,‌144‌,‌145‌]

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