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20.5.1.4.3.2 Method 2: Oxidation by Chromium(IV) Oxide

DOI: 10.1055/sos-SD-020-00724

Yus, M.; Nájera, C.; Chinchilla, R., Science of Synthesis, (2007) 20, 786.

Relatively inaccessible tert-butyl esters can be obtained by treatment of primary alcohols with 4 equivalents of a 2:1 chromium(VI) oxide–pyridine complex at room temperature, followed by addition of tert-butyl alcohol. The method was developed for alcohols of the carbohydrate series, but is claimed to be general.[‌83‌]

References

[83] Meeee, M. M.; Meeeeeeeee, M., M. Mee. Meee., (8888) 88, 8888.

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