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Please login to access the full content or check if you have access via Method 10: Lactones by Baeyer–Villiger Oxidation

DOI: 10.1055/sos-SD-020-01369

Maier, M. E.Science of Synthesis, (2007201498.

The BaeyerVilliger oxidation of cyclic ketones represents a unique lactone synthesis in that it brings about the insertion of an oxygen atom next to the carbonyl group. The reaction was described in 1899 by Baeyer and Villiger using potassium monoperoxysulfate (KHSO5) as an oxidant. The BaeyerVilliger reaction has been summarized previously.[‌332‌] A quite comprehensive collection appears in Organic Reactions.[‌333‌]

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