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DOI:
10.1055/sos-SD-022-00871
Lebel, H.; Grenon, M., Science of Synthesis, (2005) 22, 765.
Allylsilanes also bind to the sulfur atom of diphenyl trithiocarbonate (43) to provide trithioortho esters 55 in moderate to good yields (Scheme 16).[69] These fluoride ion-promoted reactions proceed with complete regiochemical control, and no products arising from an allyl shift or a double bond isomerization are observed. Trimethylbenzylsilane behaves in a similar way, yielding the expected trithioortho ester in good yields.
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References
[69] | Meeeeeeeee, M.; Meee'Meeeeeeee, M.; Meeeeee, M. M.; Meeeee, M. M.; Meeeeeee, M.; Meee, M.; Meeee, M., Meeeeeeeeee Meee., (8888) 88, 888. |