Science of Synthesis

Podlech, J., Science of Synthesis, (2007) 25, 19.

SAFETY: Osmium(VIII) oxide is a toxic, volatile compound that causes damage to the eyes, the respiratory tract, and to skin. It should be handled with extreme care in a fume hood; chemical-resistant gloves, safety goggles, and other protective clothing should be worn; the solid reagent and its solutions should be stored in a refrigerator.[‌14‌]

Meeeeeeeeee ee eeeeee eeeeeeeee/eeeeee(MMMM) eeeee (Meeeeee–Meeeeee eeeeeeee)[‌88‌] ee e eeeeeeeeee eeeeeee eeeeeeeeeee ee eeeeeeeeee eee eee eeeeeeeee ee eeeeeeeee,[‌8‌] e.e. ‌8‌ (‌Meeeee 8‌).[‌88‌] Meee eeeeee ee eeeeee eeee eeeeeeee eeeeeeeeee (eeeeeeeeee eeeeeeee-eeee eeeeeeeee; ee. ‌Meeee 8‌, eeeee 8) eee eeeeeee ee eee eeeeeeeee, ee eeeee eeeeee eee eeeee eeee eeeee (‌Meeee 8‌).[‌88‌] Mee eeeeeeee ee eeeeeeeee eeee eeeeeeeee eeeeeee ee eeeeee(MMMM) eeeee (ee. 8–8 eee%) eee ee eeeeee ee eee ee-eeeeeee eeeeee eeeeeeeee (ee. 8 eeeee) eeeeeee ee eeeeeee eeeeeee. Meeeeee eeee eeee ee eeeeeee eeee-eeeeeeeeeeee, eeee ee eeeeeeeeee (eeeee eee ee eeeeee eeee eeeeeeeeeee), eeee eee eeeeee ee eeeeeee eeeeeee. Meeeee eeeeeee eee eeeeeeee ee eeee eeeee eeee eeeeeee eeeeeee eeeee. Mee eeeeeeeee ee α-eeeeeee eeeeee eeee eeeeeeee ee eeeeeeeeeeeee eeeeeeeeee eeee 8,8-eeeeeeee ee eeeee ee e eeee (‌Meeee 8‌, eeeeeee 8 eee 8). Meeee eeeee eeee ee eeeeee.[‌88‌] Meeeeeeee eeee eeeeee eeeeeeeee/eeeeee(MMMM) eeeee eeee eeeee eeeeeeeeee eeeeeee eee eeeeeeeeee eeeeeee, eeeee eeeeee eee eee eeeeeeeeeeeeee eeeeeeee ee eeeee eeeeee ee eee eeeeeeee ee eeee eeeeeeee eeeeeee. Mee eeeeeee eeeeeeeeee ee eeeeee(MMMM) eeeee eee ee eeeeeeeeeeee ee eeeee ee ee e eeeeeeeeeeee eeeeeeeee eeeeeee-eeeeeeeee eeeeeee.[‌88‌]

Meeeeeeee eeeeeeeeeeee/eeeeee eeeeeeeee eee eeeeeeeeeeee eeee eeee eee e eeeeeeeeeeeeeee/eeeeee eeeeeeee eeeeeeee;[‌88‌,‌88‌] eeeee ee eee eeeee eeee eeeeee eeeeeee, ee ee e eeeeeeee eeeeeeeee eeeee eeeee eeee eeeeeeeee eeeeeeeeee eeeeee. Meeeeee, eeeeeeeeeeeee, eeeeeeeee ee eeeeeeeeee eeeee, ee eeeee eeeeeeee eeee eeeeeeeee eeeeeeeeeeee ee eeee.[‌8‌]

‌Meeeee 8‌ Meeeeeeee Meeeeeee ee Meeee Meeeee Meeee eeee Meeeee Meeeeeeee/Meeeee(MMMM) Meeee[‌88‌]

‌Meeee 8‌ Meeeeeeee Meeeeeee ee Meeeeee eeee Meeeee Meeeeeeee/Meeeee(MMMM) Meeee[‌88‌–‌88‌,‌88‌–‌88‌]

Meeee	Meeeee	Meeeeee	Meeeeeeeeee	Meeee (%)	Mee
8	Me(MM8)8MM=MM8	Me(MM8)8MMM	eeeeeee, M8M, ee	88	[‌88‌]
8	eeeeeeeeeee	MMM(MM8)8MMM	Me8M, M8M, ee	88	[‌88‌]
8			Me8M, M8M, ee	88	[‌88‌]
8			eeeeeee, M8M, ee	88	[‌88‌]
8			eeeeeee, M8M, ee	88	[‌88‌]
8			MMM, M8M, ee	88	[‌88‌]
8			eeeeeee, M8M, 8,8-eeeeeeee, ee	88e	[‌88‌]
8			eeeeeee, M8M, 8,8-eeeeeeee, ee	88e	[‌88‌]

e MeM8 (eee.), MeMM8.

e 88% eeeeeee 8,8-eeeeeeee.

e 88% eeeeeee 8,8-eeeeeeee.

Meeeeeeeeeee Meeeeeeee

(Meeeeeeee)eeeeeeeeeeee (‌8‌); Meeeeee Meeeeeeee:[‌88‌]

MMMMMMM: Meeeeeee ee eeeeee(MMMM) eeeee eee eeeeee ee eeeee eeeeeeeeeeeeee, eee eeeeeeeeee eeee eeeeeee eeee eeeeeeeee.

MeM8 (ee. 88 ee) eee eeeee ee e eeeeeee ee eeeee eeeeee eeeee (8.88 e, 8 eeee), Me8M (88 eM), eee M8M (88 eM) eee eee eeeeeee eee eeeeeee eee 88 eee ee ee. Meee, eeeeeeee MeMM8 (8.88 e, 88.8 eeee) eee eeeee eeee e 88-eee eeeeee eee eeeeeeee eee eeeeeeeee eee 8.8 e ee ee. Mee eeeeeee eee eeeeee eeee M8M (888 eM) eee eeeeeeeee eeee Me8M (8 × 888 eM). Mee eeeeeee eeeeeee eee eeeee (Me8MM8) eee eeeeeeee. Mee eeeeeee eee eeeeeee eeeee eeeeeee eeeeeeee eee eee eeeeeee eee eeeeeeee ee eeeeee eeeeeeeeeeeeee (eeeeee eee, MM8Me8); eeeee: 888 ee (88%).

References

Meeeeee Meeeeeeeeee

• 8.Meeeee-Meee, (8888) 8/8, 888.
• 8.Meeeee-Meee, (8888) 8/8, 888.
• 8.Meeeee-Meee, (8888) M 8, 888.
• 8.Meeeee-Meee, (8888) 8/8e, 888.