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DOI: 10.1055/sos-SD-026-00003

von Angerer, S.Science of Synthesis, (20052660.

Hypofluorous acid has been used infrequently for the oxidation of secondary alcohols to ketones because of its extreme instability, but it can be used when stabilized by complexation with acetonitrile at low temperature. A large number of aliphatic and alicyclic ketones have thus been prepared in excellent yields.[‌148‌] An example is the conversion of deca­hydronaphthalen-1-ol into octahydronaphthalen-1(2H)-one (55) (Scheme 34).

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