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26.1.1.2.12.3 Variation 3: With Other Nitrogen-Based Oxidants

DOI: 10.1055/sos-SD-026-00003

von Angerer, S.Science of Synthesis, (20052698.

3-Fluoro-3-(heptafluoropropyl)-2-(nonafluorobutyl)oxaziridine (134) oxidizes secondary alcohols, in high yields, to the corresponding ketones as demonstrated for the cyclic ketone 135 (Scheme 92).[‌371‌] This procedure is also applicable to sterically hindered alcohols. The oxidizing agent is easily accessible by epoxidation of perfluoro N-alkylimines with 3-chloroperoxybenzoic acid.[‌372‌]

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