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26.1.2.1.1 Variation 1: Using Mercury Salts

DOI: 10.1055/sos-SD-026-00062

Balaban, T. S.Science of Synthesis, (200526127.

Mercury alkoxides can be prepared in high yields by addition of mercury(II) acetate to terminal alkenes, such as hex-1-ene, dissolved in aqueous tetrahydrofuran or methanol. The analogous palladium compounds are unstable in these solutions and after reductive elimination precipitate palladium metal to form ketones (see Section 26.1.2.1.2). A one-pot combination of these two reactions for the direct conversion of alkenes into ketones has been reported. Using this method, ketones 1 are obtained in good yields (Scheme 1).[‌1‌]

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References


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