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26.1.9.4 Method 4: Palladium-Catalyzed Asymmetric Alkylations and Arylations of Alkali Ketone Enolates

DOI: 10.1055/sos-SD-026-00361

Plaquevent, J.-C.; Cahard, D.; Guillen, F.Science of Synthesis, (200526475.

A powerful application of alkali ketone enolates is the palladium-catalyzed direct α-arylation or alkylation of ketones 19. Although not fully understood, the mechanism of this type of reaction is discussed in a review.[‌49‌]

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References


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