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DOI:
10.1055/sos-SD-026-00397
Salaün, J., Science of Synthesis, (2005) 26, 563.
By using either zinc dust in acetic acid[26] or tributyltin hydride[27] one or two chlorine atoms are easily and selectively removed from α,α-dichlorocyclobutanones.[28] Thus 7,7-dichlorobicyclo[3.2.0]hept-2-en-6-one (31), formed by [2+2] cycloaddition of dichloroketene to cyclopentene (see Section 26.2.1.7.2), is reduced by zinc/acetic acid to yield bicyclo[3.2.0]hept-2-en-6-one (33) in 95% yield via the endo-monochloro adduct 32 (Scheme 12).[28]
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References
| [26] | Mee, M.; Meeee, M. M.; Meeeeeee, M. M., Meeeeeeeeee Meee., (8888), 8888. |
| [27] | Meeee, M. M.; Meee, M. M.; Mee, M., Me.; Meeee, M. M., Me., M. Me. Meee. Mee., (8888) 88, 8888. |
| [28] | Meeeee, M. M., M. Mee. Meee., (8888) 88, 8888. |
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- 8.Meeeee-Meee, (8888) M 88e, 888.
- 8.Meeeee-Meee, (8888) M 88e, 888.
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