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26.3.2.1.1 Method 1: Photodecarbonylation of Cyclobutanediones

DOI: 10.1055/sos-SD-026-00451

Salaün, J.Science of Synthesis, (200526612.

Irradiation of cyclobutane-1,3-dione 6[‌27‌] in methanol or ethanol at 4075°C provides the cyclopropanone methyl and ethyl hemiacetals 35 (R1=Me, Et) respectively, in 5580% yields (Scheme 13).[‌58‌,‌59‌]

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