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26.11.2.1.5 Method 5: Radical Acylation

DOI: 10.1055/sos-SD-026-01162

Harrison-Marchand, A.; Chataigner, I.; Maddaluno, J.Science of Synthesis, (2005261244.

Radical acylation is an interesting method for synthesizing chalcogeno ketones. In particular, β-alkoxy and γ-sulfono ketones are readily prepared by the addition of acyl radicals to chalcogeno-substituted alkenes. The chemistry of acyl radicals has been reviewed elsewhere.[‌205‌]

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References


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