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DOI:
10.1055/sos-SD-027-00002
Aggarwal, V.; Richardson, J., Science of Synthesis, (2004) 27, 63.
The phase-transfer-catalyzed transfer of anionic reactants, such as basic hydroxide anions, from an aqueous to an organic phase by quaternary ammonium salts is a commonly used procedure for the deprotonation of sulfonium salts. Using aqueous sodium hydroxide and dichloromethane in the presence of a quaternary ammonium salt, typically tetrabutylammonium chloride or benzyltriethylammonium chloride, a range of sulfonium ylides can be prepared, including those that are unsubstituted,[131,200] those bearing aryl groups,[201] and carbonyl stabilizing groups.[202]
References
| [131] | Meee, M.; Meeeee, M., Meeee. Meee., (8888) 88, 888; Meeee. Meee. Mee. Me. Meee., (8888) 88, 888. |
| [200] | Meeee, M. M.; Meeee, M. M.; Meeee, M. M.; Meeee, M. M., Meeeeeeee, (8888), 88. |
| [201] | Meeee, M.; Meeeeee, M. M.; Meeee, M., Meeeeeeeeee Meee., (8888) 88, 88. |
| [202] | Meee, M.-M.; Mee, M.-M.; Mee, M.-M.; Mee, M.-M.; Meee, M.-M., M. Meee. Mee., Meeeee Meeee. 8, (8888), 88. |
Meeeeee Meeeeeeeeee
- 8.Meeeee-Meee, (8888) M 88-8, 8888.
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