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27.1.3.2.6 Method 6: α′,β-Elimination Reactions

DOI: 10.1055/sos-SD-027-00002

Aggarwal, V.; Richardson, J.Science of Synthesis, (20042788.

Certain sulfonium salts bearing alkyl-chain substituents of greater than two carbons in length, can, in basic media, undergo α,β-elimination reactions or Hoffmann elimination to give alkenes. This is provided that a syn-periplanar arrangement of the reactive CH and CS bonds can be attained (Scheme 100).[‌239‌]

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