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29.2.6.1.2.1 Variation 1: Synthesis from gem-Dihaloalkanes

DOI: 10.1055/sos-SD-029-00061

Rowlands, G. J.Science of Synthesis, (200729106.

The standard procedure for the preparation of 1,1-diiodoethane 128 involves an interesting exchange reaction in which 1,1-dichloroethane 127 is converted into the desired product 128 in the presence of aluminum trichloride with iodoethane as the iodine source (Scheme 52).[‌278‌] The same transformation can also be achieved with aluminum triiodide in carbon disulfide.[‌279‌]

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