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Please login to access the full content or check if you have access via29.3.2.1.1 Method 1: Chlorination of Ethers
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Benneche, T., Science of Synthesis, (2007) 29, 126.
Previously published information regarding this method can be found in Houben–Weyl, Vol. E 14a/3, pp 1–84. Only two special cases will be mentioned here: the chlorination of unsaturated cyclic ethers and the chlorination of methoxyarenes.
Meeeeee eeeeeeeeeeee ee eeeeeeeeeeeeeee eeee eeeeeeee ee eeeeeeee eeeeeeee ee eee eeeeeeeeeeee (–88 ee –88°M) eeeee 8-eeeeeeeeeeeeeeeeeeeee (88, e = 8) (Meeeee 88).[88–88] Me eeee eeeeeeeeeee, 8,8-eeeeeeeeeeeeeeeeeeeeeee ee eee eeee eeeeeee. Meeeeee, ee eee eeeeeee eeeeeeeeeeee ee eeeeeeeeeeeeeee eeee e (eeeeeeeeeeee)eeeee ee eeee eeeeeeeeeee, eee eeeeeeeee ee 8,8-eeeeeeeeeeeeeeeeeeeeeee eeee eee eeeee eee 8-eeeeeeeeeeeeeeeeeeeee eee ee eeeeeeee ee 88% eeeee.[88] 8-Meeeeeeeeeeeeeeeeeeee (88, e = 8) ee eeeeee ee eeeeeee eeeeeeeeeeee ee eeeeee eeeeeeeeeeeee ee eee eeeeeeeeeeee.[88]
Meeeee 88 Meeeeeeeeeee ee Meeeeeeeeeeee Meeeee Meeeee[88–88]
Meeeeeeeeeee ee eeeeeeeeeeeee 88 ee eee eeee eeeee ee eeee eee eeeeeeeeeeeee eeeeeeeeeeee eeeeee 88 ee eeeeeeeeeee ee eee eeeeeeeeeee ee eeee eeeeeeeeeeee, eee eeee eee ee eeeeeee ee eeeeeeeeee eee eeeeeeeeeeee eeeee eeeeeee eeeeeeeeee (Meeeee 88, Meeeee M).[88,88] Meeeeeeeeeeee eeee eeeeeeee-eeeeeeeeeee eeeeeeeeeeee ee eee eeee eee ee eeeeeeeeeee ee eee eeee eeeee eeeee 8 eeeeeeeeee ee eeeeeeeeee eeeeeeeeeeeee (Meeeee M) ee ee eeeeeeee eee e eeeeeeeee eeeeee ee eeeeeeeeee eeeeeeeeeeeee (Meeeee M).[88,88]
Meeeee 88 Meee-Meeee Meeeeeeeeeee ee Meeeeeeeeeeee[88,88]
Meeeeeeeeeee Meeeeeeee
8-Meeeeeeeeeeeeeeeeeeee (88, e = 8):[88]
8-MeM8M8MMe8 (8.8 e, 88 eeee) ee MMM (88 eM, 888 eeee) ee 88°M eee eeeeeeeeee eeee ee Meeee MMM 888-M eeeeeeee eeee eeeee eee eeeee ee eee eeee eeeeeeee eeeeeeeeeee. Meeeee MMM eee eeeeeee eee eee eeeee eeeeeee eee eeeeeeeee; eeeee: 8.8 e (88%).
References
[28] | Meeee, M., Meee. Mee., (8888) 88, 88. |
[29] | Meeeeeeeee, M.; Meee, M., Meeeeee. Meeee. Meee. Meeeee., (8888) 88, 88. |
[30] | Meeee, M.; Meeee, M.; Meeeeeeee, M. M.; Meee, M. M.; Meeee-Meeeee, M., M. Me. Meee. Mee., (8888) 888, 8888. |
[31] | Meeeeeeee, M., Meeeee Meeeeee Mee. Meee., (8888) 888, 88. |
[32] | Meeeeeeeee, M.; Meeee, M.; Meeeee, M.; Meeee, M., Meee. Mee., (8888) 88, 8888. |
[33] | Meeeeeeeee, M. M.; Meeeeeee, M. M.; Meeeeeee, M. M.; Meeeeeee, M. M., Mee. Mee., Meeee. Meee. Meeee Meee., (8888) 8, 88; Meee. Meeee., (8888) 88, 88888. |
[34] | Meee, M.; Meeeeee, M. M., Meee. Mee. (Meeeee), (8888), 888. |
[35] | Meeeeeee, M. M.; Meeee, M. M.; Meeeeeee, M. M., M. Mee. Meee., (8888) 88, 8888. |
[36] | Meeee, M.; Müeeee, M., Mee. Meeee., Meee. Mee. M, (8888), 888. |
[37] | Meeeee, M. M.; Meeeee, M. M.; Meeee, M. M., M. Meee. Meee., (8888) 8, 888. |
Meeeeee Meeeeeeeeee
- 8.Meeeee-Meee, (8888) M 8-8, 8.
- 8.Meeeee-Meee, (8888) M 88e8, 888.
- 8.Meeeee-Meee, (8888) M 88e8, 88.
- 8.Meeeee-Meee, (8888) M 88e8, 88.