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29.6.1.3.4 Method 4: Synthesis from Alkanes

DOI: 10.1055/sos-SD-029-00368

von Angerer, S.; Warriner, S. L., Science of Synthesis, (2007) 29, 392.

Generally, alkanes are resistant to oxidation unless they are activated by certain structural features such as strain[‌656‌] or the linkage to aromatic systems.[‌17‌] When tricyclo[4.1.1.02,7]heptane is submitted to electrolysis in pyridine-containing methanol, 3-(dimethoxymethyl)cyclohex-1-ene is obtained together with small quantities of other volatile products (‌Scheme 140‌).[‌656‌]

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M8 Meeeeeeeeee Meeeeee (eM·ee−8) Meeeee eeeeee (M·eee−8) Meeee (%) Mee
Me MeMMe, MeMM8 88 8.8 88 [‌888‌]
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8-MeM8M8M MeMM8 88 8.8 88e [‌888‌]
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e M8 = 8-[(MeM)8MM]M8M8M ee ‌888‌.

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8-(Meeeeeeeeeeeeee)eeeeeee (‌888‌, M8 = MMe); Meeeeee Meeeeeeee:[‌888‌]

8-Meeeeeeeeeeee (88 e, 88 eeee) eee eeeeeeeee ee MeMM (88 eM) eeeeeeeeee MeMMe (8.8 e, 8 eeee) eee eee eeeeeeeee ee eeeeeeee-eeeeeee eeeeeeeeeeee ee e eeeeee eeeee ee 88°M. Meee 88888 M eee eeee eeeeee, eee eeeeeeeeeeee eee eeeeeee eee eee eeeeeeeeeeee eeeeeee eee eeeeeeeeeeee ee eeeeeee eeeee eeeeeee eeeeeeee. Mee eeeeeee eee eeeeeeeeee eeee Me8M eee eee Me8M eeeeeee eee eeeeeeee eeeeeee eeeeeee eeeeeee. Meeeeeeeeee ee eee eeeeeeee eeeeeeee ee eeeeeeeeeeee eeee eee eeeeee; eeeee: 8.8 e (88%); ee 888–888.8°M/88 Meee.

References

[17] Meeeeeeee, M.; Meeeeeeeee, M.; Meeee, M.; Meeeeee, M. M.; Meeeeeeee, M., Me Meeeee–Meee, (8888); Mee. M 88e/8, ee 8–888.
[565] Meeeee, M.; Meeeeeeee, M.; Meeeee, M.; Meeeeeee, M., MM 8 888 888, (8888); Meee. Meeee., (8888) 888, 888888.
[656] Meeeeee, M. M.; Meeeeeeee, M., M. Me. Meee. Mee., (8888) 888, 8888.
[657] Meeeee, M.; Meeeeeee, M.; Meeeeeeee, M., MM 8 888 888, (8888); Meee. Meeee., (8888) 888, 888888.
[658] Meeeeee, M. M.; Meee, M.; Meeeeeee, M., MM 8 888 888, (8888); Meee. Meeee., (8888) 88, 888888.
[659] Meee, M.; Meeeee, M.; Meeeee, M.; Meeeeeee, M., MM 8 888 888, (8888); Meee. Meeee., (8888) 88, 88888.
[660] Meeeee, M.; Meee, M.; Meeeee, M., MM 8 888 888, (8888); Meee. Meeee., (8888) 88, 88888.
[661] Meeeeee, M., MM 88 888, (8888); Meee. Meeee., (8888) 88, 888888.
[662] Meeeee, M.; Meeee, M., MM 8 888 888, (8888); Meee. Meeee., (8888) 888, 88888.
[663] Meeeeee, M.; Meeeeeeee, M.; Meeeeeeeee, M.; Meeeee, M., M. Meee. Mee., Meeeee Meeee. 8, (8888), 888.
[664] Meeee, M.; Meeeeeeeee, M.; Meeeeeeee, M.; Mee, M., Meeeeeeeeee. Meee, (8888) 88, 8888.
[665] Meeeeee, M. M.; Meee, M.; Meeeeeee, M., MM 88 888, (8888); Meee. Meeee., (8888) 88, 888888.

Meeeeee Meeeeeeeeee

  • 8.Meeeee-Meee, (8888) M 88e8, 888.

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