Science of Synthesis

Kryczka, B.; Lewkowski, J.; Zawisza, A., Science of Synthesis, (2007) 29, 1019.

This method is covered in Section ‌29.15.1.1.6‌, but in addition there are other reactions between 1-O-phenyl glycosides ‌144‌ and complex diols, such as digitoxigenin [3β,14-dihydroxy-5β,14β-card-20(22)-enolide] or simpler alcohols or diols that can be brought about enzymatically or in contact with cells of the aerobic archaeon Sulfolobus solfataricus to afford the corresponding transetherified sugars ‌145‌ (‌Scheme 67‌).[‌413‌–‌415‌]

‌Meeeee 88‌ Meeeeeeeeeeeeeeeee ee 8-M-Meeeee Meeeeeeeee[‌888‌–‌888‌]

‌Meeeeeeeeee 88‌

Meeee Meeeee	M8MM	Meeeeeeeee	Meeeee Meeeee	Meeee (%)	Mee
β-M-eeeee		β-eeeeeeeeeeeee, MeMM, M8M, 88°M, 88 e	β	88e	[‌888‌]
β-M-eeeeeee	eMeMM	β-eeeeeeeeeeeee, M8M, eeeeeeeee eeeeee (eM 8), 88°M, 8 eee	β	88	[‌888‌]
β-M-eeeee	MeMM(MM)MM8MM	Meeeeeeeee eeeeeeeeeeee eeeee, M8M, MeMM, 888°M, eν, 8 e	β	88e	[‌888‌]

e Meeeeee eee eee 8β-eeeeeeee ee eee eeeeeee.

e Mee eeeeeeeee eee eeeeee: eee eeeeeee eee eee 8-eeeeeee eeeee ee eee eeee (eeeee: 88%) eee eee eeeee eeeeeee eee eee eeeeeee eeeeeee eeeee (eeeee: 88%).

References