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30.5.5.1.1 Method 1: Aminomethylation of Sodium Hydrogen Telluride

DOI: 10.1055/sos-SD-030-00466

Murai, T.; Yoshimatsu, M.Science of Synthesis, (200730634.

Condensation reaction of primary arylamines with formaldehyde, followed by reaction with sodium hydrogen telluride, gives cyclic Te,N-acetals 75 along with the 1,2,4-ditellurazolidines 76 (Scheme 44).[‌133‌] The acetals 75 are obtained as greenish yellow solids, and their aerobic oxidation leads to the compounds 76.

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