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31.4.1.2.7.2.1 Variation 1: Azidations with (Diazidoiodo)benzene In Situ

DOI: 10.1055/sos-SD-031-00109

Zhdankin, V. V.Science of Synthesis, (200731222.

(Diazidoiodo)benzene [PhI(N3)2], generated in situ from iodosylbenzene and trimethylsilyl azide, finds some practical application as an efficient reagent for the introduction of the azido function into organic molecules.[‌5‌] Particularly useful are the azidations of triisopropylsilyl enol ethers 257 affording β-azido adducts 258 in excellent yields and the N-alkylazidation of N-alkylamines 259 (Scheme 92).[‌362‌‌364‌]

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