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Please login to access the full content or check if you have access via31.4.1.2.7.2.1 Variation 1: Azidations with (Diazidoiodo)benzene In Situ
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DOI:
10.1055/sos-SD-031-00109
Zhdankin, V. V., Science of Synthesis, (2007) 31, 222.
(Diazidoiodo)benzene [PhI(N3)2], generated in situ from iodosylbenzene and trimethylsilyl azide, finds some practical application as an efficient reagent for the introduction of the azido function into organic molecules.[5] Particularly useful are the azidations of triisopropylsilyl enol ethers 257 affording β-azido adducts 258 in excellent yields and the N-alkylazidation of N-alkylamines 259 (Scheme 92).[362–364]
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References
[5] | Meeeeeee, M. M.; Meeee, M. M., Meee. Mee., (8888) 888, 8888. |
[362] | Meeeee, M.; Meeeee, M.; Meeee, M. M.; Mee, M. M.; Meeee, M., M. Me. Meee. Mee., (8888) 888, 8888. |
[363] | Meeeee, M.; Meeeee, M.; Meeee, M., M. Me. Meee. Mee., (8888) 888, 8888. |
[364] | Meeeee, M.; Meeeee, M.; Meeee, M., Meeeeeeee, (8888), 888. |
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