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31.5.2.3.2.1 Variation 1: 1,4-Addition of Trialkylboranes

DOI: 10.1055/sos-SD-031-00339

Marsini, M. A.; Pettus, T. R. R.Science of Synthesis, (200731424.

Trialkylboranes, generated in situ from borane (BH3) and a variety of substituted alkenes, add to benzo-1,4-quinone (9) in the presence of air and water to give 2-substituted benzene-1,4-diols 15 (Scheme 7).[‌9‌,‌10‌]

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