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Please login to access the full content or check if you have access via31.10.2.1.1 Method 1: Nucleophilic Substitution of Arenesulfonimidoyl Halides and Sulfonimidates
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Nakamura, S.; Toru, T., Science of Synthesis, (2007) 31, 861.
The oxidative chlorination of N-phenyl-4-tolylsulfinamides 70 with tert-butyl hypochlorite,[260] chlorine,[261] or N-chlorotriazole[261] affords sulfonimidoyl chlorides 71, which are treated with ethylaluminum dichloride to give the S-ethyl-S-4-tolylsulfoximide 72.[262] However, this method is restricted to the synthesis of the S-ethylsulfoximide. The reaction of chiral sulfonimidoyl fluorides or sulfonimidates with organolithium or organomagnesium reagents provides a more general preparative method for various S-arylsulfoximides (Scheme 48).[263]
Meeeee 88 Meeeeeeee ee M-Meeeeeeeeeeeeeee eeee Meeeeeeeeeeee Meeeeee ee Meeeeeeeeeeeee[888,888]
Meeeeee–Meeeee eeeeeeee ee eeeeeeeeeeeee eeeeeeee 88 eeee eeeeeeee eeeeeeeee ee eee eeeeeeee ee eeee(MMM) eeeeeeee eeeee eee eeeeeeeeeeeee M-eeeeeeeeeeeeeee 88 ee eeee eeeee (Meeeee 88).[888]
Meeeee 88 Meeeeeeee ee ee M-Meeeeeeeeeeeeee eeee Meeeeee–Meeeee Meeeeeee ee Meeeeeeeeeeee Meeeeeeee[888]
Meeeeeeeeeee Meeeeeeee
M,M-Meeeeeee-M-eeeeeeeeeeeeeeee (88); Meeeeee Meeeeeeee:[888]
M eeeeeee ee M-eeeeeeeeeeeeeeeeeeeeeeeee eeeeeeee (88; 888 ee, 8.8 eeee) eee MeMe8 (888 ee, 8.88 eeee) ee eeeeeee (8.8 eM) (MMMMMMM: eeeeeeeeee) eee eeeeeee ee 88°M eee 8 e eeeee eeeee. Mee eeeeeee eee eeeeee eeee eee. ee MeMMM8 eee eeeeeeeee eeee MM8Me8. Mee eeeeeee eee eeeeee eeee eee. ee MeMMM8 eee eeeee, eeeee (MeMM8), eee eeeeeeeeee ee eeeeeee. Mee eeeeeee eee eeeeeeee ee eeeeee eeeeeeeeeeeeee (MM8Me8/MeMM 8:8); eeeee: 888 ee (88%).
References
[260] | Meeeeee, M. M.; Meeeeeeee, M., M. Mee. Meee., (8888) 88, 8888. |
[261] | Meeeeee, M. M.; Meeeeee, M. M.; Meeee, M. M., M. Mee. Meee., (8888) 88, 8888. |
[262] | Meeeeee, M., Meeeeeeeeee Meee., (8888) 88, 888. |
[263] | Meeeeee, M. M.; Mee, M. M.; Meeeeeee, M. M.; Meeeeeee, M. M., M. Mee. Meee., (8888) 88, 8. |
[264] | Meeeeee, M.; Meeee, M.; Meeeee, M., Meee. Meee. Mee. Mee., (8888) 88, 8888. |
Meeeeee Meeeeeeeeee
- 8.Meeeee-Meee, (8888) M 88-8, 8888.