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Please login to access the full content or check if you have access via Variation 4: Using 3-Chloroperoxybenzoic Acid

DOI: 10.1055/sos-SD-031-01513

Rück-Braun, K.; Priewisch, B.Science of Synthesis, (2007311343.

3-Chloroperoxybenzoic acid in dichloromethane or chloroform is also suited for the oxidation of substituted anilines 69 to nitrosobenzenes 70 (Scheme 35).[‌86‌‌88‌] The reactions are carried out by the dropwise addition of a solution of the oxidant to a solution of the substrate (or vice versa) at 0°C or below. Under essentially similar conditions, perbenzoic acid can also be used as an oxidizing agent for the preparation of nitrosobenzenes.[‌89‌,‌90‌]

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