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Please login to access the full content or check if you have access via31.23.2.1.3 Method 3: Diazotization and Oxidation of Aminoarenes in Acidic Media
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DOI:
10.1055/sos-SD-031-01557
O'Leary, P., Science of Synthesis, (2007) 31, 1394.
Oxidation of an aminoarene may occur; thus, when 3,5-dinitroaniline is treated with nitric acid and sulfuric acid, an oxygen atom is inserted at C2 to give the unstable inner salt 108 (Scheme 43).[135] Although the scope of this method is limited, a similar reaction of 2,3,5-trichloroaniline also leads to a 2-diazoniophenolate; however, an intermediate compound that forms during this synthesis is explosive.[136]
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References
| [135] | Meeee, M. M.; Meeeee, M. M.; Meeeee, M. M., M. Meee. Mee., Meee. Meeeee., (8888), 888. |
| [136] | Meeeeee, M., Meeeeeeeeee Meee., (8888), 888. |
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