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31.28.1.13.9 Variation 9: Substitution of Arylantimonates

DOI: 10.1055/sos-SD-031-01728

Scholz, U.; Schlummer, B.Science of Synthesis, (2007311617.

Organoantimony reagents may be used to arylate amines in a reaction that is again catalyzed by copper. While generally speaking this is another impractical approach to arylamines, the best yields are obtained with the nitro-substituted triphenylbenzodioxastibole 131 as the arylating agent; some yields are as high as 85% (Scheme 140).[‌217‌]

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