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DOI:
10.1055/sos-SD-032-00570
Trauner, D., Science of Synthesis, (2008) 32, 537.
Enols such as 14 can be generated as transient species through sigmatropic rearrangements, such as the oxy-Cope rearrangement (Scheme 8). Again, the products of this reaction are generally isolated in the oxo form 15. Due to the enormous rate acceleration that is observed upon deprotonation, the oxy-Cope rearrangement has been largely supplanted by the anionic oxy-Cope rearrangement, which yields enolates.[16]
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References
| [16] | Meeeee, M. M.; Meeee, M., Me., M. Me. Meee. Mee., (8888) 88, 8888. |
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