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32.5.3.1.4 Formation of the C=C Bond by Condensation Reactions

DOI: 10.1055/sos-SD-032-00627

Milata, V.; Rádl, S.; Voltrová, S.Science of Synthesis, (200832648.

More information on the formation of C=C bonds by alkenylation to give enol ethers can be found in HoubenWeyl, Vol.E 15, pp140184. The following sections cover five main methods: the reactions of carbonyl derivatives with compounds possessing an acidic methylene group (Section 32.5.3.1.4.1), Wittig condensation (Section 32.5.3.1.4.2), McMurry-type couplings (Section 32.5.3.1.4.3), alkylidenation by titanium alkylidene derivatives (Section 32.5.3.1.4.4), and the reaction of Fischer carbene complexes with acetylenes (Section 32.5.3.1.4.5).


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