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33.1.8.1.1.10.3 Variation 3: Metal-Catalyzed Addition of Thiols and Their Borabicyclo Derivatives to Alkynes

DOI: 10.1055/sos-SD-033-00087

Drabowicz, J.; Kiełbasiński, P.; Mikołajczyk, M.Science of Synthesis, (200733143.

The niobium cyclopentadiene-stabilized thiolate 113, prepared in situ, reacts with perfluoroalkylated acetylenes to give isomeric perfluoroalkyl vinyl sulfides 114A/114B (Scheme 51).[‌103‌]

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M8 M8 M8 Meeee (M/M) Meeee (%) Mee
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Mee-8-eeee Meeeeeee 888; Meeeeee Meeeeeeee:[‌888‌]

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References