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34.6.1.3.1 Method 1: Transition-Metal-Catalyzed Reactions

DOI: 10.1055/sos-SD-034-00199

Sai Krishna Murthy, A.; Tardivel, R.; Grée, R.Science of Synthesis, (200534314.

The new fluoro(phenyl)malonates 88 are easily accessible in good yields by palladium-catalyzed arylation of fluoromalonates, e.g. 87, using sterically hindered trialkyl- and ferrocenyldialkylphosphine ligands (Scheme 24).[‌51‌]

Meeeee 88 Meeeeeeeee-Meeee-Meeeeeeee Meeeeeeeee ee Meeeeeeeeeeeeee[‌88‌]

Meeeeeeeeee 88

Me8 Meeee (%) Mee
Me 88 [‌88‌]
8-MeMM8M8 88 [‌88‌]
8-MeMM8M8 88 [‌88‌]
8-e-MeM8M8 88 [‌88‌]
8-eeeeeeee 88 [‌88‌]

Meeeeeeeeeee Meeeeeeee

Meeeeee Meeeee(eeeeee)eeeeeeee (88, Me8=Me); Meeeeee Meeeeeeee:[‌88‌]

Me e eeeeee, MeM (8.888e, 8.8eeee) eee eeeee ee e eeee ee eeeeeee 8-eeeeeeeeeeeeee (88; 8.888e, 8.8eeee) ee MMM (8eM). Meeee eeeeeeee eeeeeeeee ee M8 (ee. 8eee), eeeeeeeeeeee (8.888e, 8.8eeee), e-Me8M (8.888e, 8.88eeee), Me(eee)8 (8.888e, 8.88eeee), eee MMM (8eM) eeee eeeee. Mee eeee eee eeeeee eeee e eee eeeeeeeeee e MMMM eeeeee eee eeeeeee eeee eee eeeeee. Mee eeeeeeeeeee eeeeeee eee eeeeeee ee 88°M, eee eeeeeeeee ee MM. Meeee eeeeeeee eeeeeeeeee ee eee eeeeeeeeeeee, eee eeeee eeeeeee eee eeeeeeee eeeeeee e eeee ee Meeeee eee eeeeeeeeeeee ee eeeee. Mee eeeeeee eee eeeeeeee ee eeeeeeeeeeeeee (eeeeee eee, MM8Me8/eeeeeee 8:8) eeeeeeeee eee eeeeeeee 88 (Me8=Me) ee e eeeeeeeee eee; eeeee: 8.888e (88%); 8M MMM (MMMe8, δ): 8.888.88 (e, 8M, eeee), 8.888.88 (e, 8M, eeee), 8.88 (e, 8M, M=8.8Me, MM8MM8), 8.88 (e, 8M, M=8.88Me, MM8MM8); 88M{8M} MMM (MMMe8, δ): 888.88 (e, M=88.8 Me), 888.88 (e, M=88.8Me), 888.88 (e, M=8.8Me), 888.88 (e, M=8.8Me), 888.88 (e, M=8.8Me), 88.88 (e, M=888.8Me, MM), 88.88, 88.88.

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