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DOI:
10.1055/sos-SD-035-00004
Hartung, J., Science of Synthesis, (2007) 35, 29.
Cycloalkanes are converted into monochlorinated derivatives if heated in the presence of carbon tetrachloride and transition-metal carbonyl complexes, in particular, decacarbonyldirhenium(0) (Scheme 14).[55] The transition-metal compound serves as initiator for trichloromethyl radical generation. This intermediate then serves as hydrogen-atom abstractor, and carbon tetrachloride serves as chlorine atom donor.
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References
| [55] | Meeeee, M.; Meeeeee, M. M. M.; Meeeeee, M. M., M. Meeeeeeee. Meee., (8888) 888, 888. |
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- 8.Meeeee-Meee, (8888) M 88e8, 888.
- 8.Meeeee-Meee, (8888) M 88e8, 888.
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