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36.1.1.1.8 Variation 8: Oxidation with Ruthenium Compounds

DOI: 10.1055/sos-SD-036-00003

Porter, M. J.Science of Synthesis, (20083629.

Ruthenium(VIII) oxide, generated in situ from ruthenium(III) chloride and sodium periodate, is a powerful oxidant for various classes of organic substrate. Alkanes 22 containing tertiary CH bonds are readily converted into the corresponding tertiary alcohols 23 (Table 6),[‌75‌‌77‌] whereas simple cyclic alkanes are oxidized further to give ketones[‌78‌,‌79‌] or (with CC bond cleavage) dicarboxylic acids.[‌78‌]

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