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Please login to access the full content or check if you have access via Variation 2: Oxidation of Alkoxysilanes with Hydrogen Peroxide

DOI: 10.1055/sos-SD-036-00003

Porter, M. J.Science of Synthesis, (20083636.

Oxidation of mono-, di-, or trialkoxysilanes to alcohols can be carried out with hydrogen peroxide under neutral or basic conditions to give primary or secondary alcohols (Table 10).[‌127‌‌131‌] The most commonly used procedure is the same as that employed for alkyltrichlorosilanes (see Section, although potassium fluoride or the base may sometimes be omitted. Potassium hydrogen difluoride has also been used as a fluoride source. Cyclic silyl ethers can also be oxidized under the same conditions to give diols.[‌132‌]

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