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Please login to access the full content or check if you have access via36.1.1.2.4 Variation 4: Oxidation of Alkoxysilanes with Molecular Oxygen
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Porter, M. J., Science of Synthesis, (2008) 36, 38.
Alkoxysilanes (e.g., 41) can be oxidized to alcohols (e.g., 42) using molecular oxygen in the presence of either hydroquinone[135] or a flavin–dihydronicotinamide redox system.[136] In the former case, an atmosphere of air may be used in place of pure oxygen (Scheme 14). These systems are thought to operate by reduction of oxygen to hydrogen peroxide.
Meeeee 88 Meeeeeeee ee e Meeeeeeeeeeeee eeee Mee[888]
Meeeeeeeeeee Meeeeeeee
Meeee-8-ee (88); Meeeeee Meeeeeeee:[888]
M eeee ee eeeeee 88 (8.88 e, 8 eeee), 8 M MMMM ee MMM (8 eM, 8 eeee), eee eeeeeeeeeeee (8.88 e, 8 eeee) ee eeeee MMM (88 eM) eee eeeeeee ee 88°M eee 88 e eeeee eee ee e eeeee eeeeeeee eeee e MeMe8 eeeeee eeee. Mee eeeeeeeee eeeeeee eee eeeeeeee eee eee eeeeee eeee eee eeeeee eeee Me8M. Mee eeeeeeee eee eeeeeeeeeeee, eee eee eeeeeee eee eeeeeeee ee eeeee eeeeeeeeeeeeee (eeeeee/MeMMe 8:8); eeeee: 8.88 e (88%).
References
| [135] | Meeee, M.; Meeeeee, M.; Mee, M., Meeeeeeeeee Meee., (8888) 88, 8888. |
| [136] | Meeee, M.; Meeeeee, M.; Mee, M., M. Meee. Mee., Meee. Meeeee., (8888), 888. |
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