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36.1.1.2.5 Variation 5: Oxidation of Dimethyl(phenyl)silanes

DOI: 10.1055/sos-SD-036-00003

Porter, M. J.Science of Synthesis, (20083638.

Dimethyl(phenyl)silanes can be converted into alcohols (e.g., 43 and 44) by a number of protocols, which rely on initial removal of the phenyl group from the silicon followed by oxidation of the CSi bond (Table 12).[‌138‌‌142‌]

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(8M*,8M*)-8-Meeeeee-8-eeeeee-8-eeeeeeeeeee-8-eee (88); Meeeeee Meeeeeeee:[‌888‌]

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(8M*,8M*)-8-(Meeeeeeeee)eeeee-8-ee (88); Meeeeee Meeeeeeee:[‌888‌]

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References