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36.7.1 Product Subclass 1: 1,2-Diols

DOI: 10.1055/sos-SD-036-00589

Nativi, C.; Roelens, S.Science of Synthesis, (200836757.

1,2-Diols play an important role in biological systems. They have also found frequent use as starting materials for the enantio- or diastereoselective syntheses of natural products and drugs, as chiral auxiliaries, and as transition-metal ligands for asymmetric synthesis and catalysis.[‌3‌,‌4‌] A number of powerful asymmetric reactions for the synthesis of syn-1,2-diols have emerged; however, the diastereoselective syntheses of anti-1,2-diols still remain less common than those of the syn-analogues.

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