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36.12.9.1.2 Method 2: Synthesis by Transmetalation

DOI: 10.1055/sos-SD-036-00789

Morey, J. V.; Wheatley, A. E. H.Science of Synthesis, (2008361129.

The reaction of butyllithium with various other metal alcoholates has been reported. For example, a classic synthesis of the strong base butylsodium (89) features the reaction of butyllithium with sodium tert-butoxide (88) in hexane. This procedure also gives the transmetalated product lithium tert-butoxide (90) as a byproduct (Scheme 31).[‌55‌]

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