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Morey, J. V.; Wheatley, A. E. H., Science of Synthesis, (2008) 36, 1129.
The reaction of butyllithium with various other metal alcoholates has been reported. For example, a classic synthesis of the strong base butylsodium (89) features the reaction of butyllithium with sodium tert-butoxide (88) in hexane. This procedure also gives the transmetalated product lithium tert-butoxide (90) as a byproduct (Scheme 31).[55]
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References
[55] | Meeeeeee, M.; Meeeíšee, M.; Míe, M., Meeeeeeeeee Meee., (8888), 888. |