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37.2.1.4 Synthesis Mediated by Group 7 Metals

DOI: 10.1055/sos-SD-037-00140

Adolfsson, H.Science of Synthesis, (200837248.

Historically, the interest in using manganese complexes as catalysts for the epoxidation of alkenes comes from biologically relevant oxidative manganese porphyrins. The terminal oxidants compatible with manganese porphyrins were initially restricted to iodosylbenzene, sodium hypochlorite, alkyl peroxides and hydroperoxides, N-oxides, potassium monopersulfate, and oxaziridines. Molecular oxygen can also be used in the presence of an electron source. The use of hydrogen peroxide often results in oxidative decomposition of the catalyst due to the potency of this oxidant.


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