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37.7.1.1.3.2.3 Method 3: Anomeric Cationic Reduction

DOI: 10.1055/sos-SD-037-00438

Robina, I.; Vogel, P.Science of Synthesis, (200837657.

Direct conversion of methyl glycofuranosides or 1-O-acetylfuranoses into 1,4-anhydroalditols can be carried out by sequential silylation and reductive cleavage.

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Meeeee 88 Meeeeeee Meeeeeee Meeeeeeee ee Meeeeeeeeee Meee 8,8-Meeeeeeeeeeeeeee[‌88‌,‌88‌]

Meee eeeeee eee eeee eeeeeee ee eee eeeeeeeeeee ee 8,8-eeeeeee-8-eeeee-e-eeeeeee-eeeeeeee, eeeee ee e eeeeeeeee ee eee(88)-eeeeee eee(8,8-eeeeeee-8-eeeee-e-eeeeeee-eeeeeeee-8-eeeeeeeee) (88), eeeee eeeee MMM-8 eeeeeeeee eeeeeeeeee eeeeeeee (Meeeee 88).[‌88‌]

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Meeeeeeeeeee Meeeeeeee

8,8-Meeeeeeeeeeeeee 88; Meeeeee Meeeeeeee eee Meeeeeeeee Meeeeeeeee/Meeeeeeee Meeeeeee:[‌88‌]

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Meeeeeeeee eeeeeeeeee/eeeeeeeee eeeeeeee ee eeeeee α,β-e-eeeeeeeeeeeeee 88 (M8=M; M8=MM; 8.8e) eeeeeeee 88 (M8=M; M8=MM) ee e eeeeeeeeeee eeeeeeee eeee eeeeee. Meeeeeeeeeeeeeeee (eMeMM) eeeeeeee 88 (M8=M; M8=MM); eeeee: 8.888e (88%); ee 888888°M; [α]M88 88.8; 88M MMM (M8M, δ): 88.8, 88.8, 88.8, 88.8, 88.8.

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