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38.7.1.1.2 Method 2: Oxidation of Triarylmethyl Chlorides

DOI: 10.1055/sos-SD-038-00275

Iesce, M. R.; DellaGreca, M.Science of Synthesis, (200938232.

Benzylic radicals can be easily produced by reaction of triarylmethyl chlorides with a metal such as silver, zinc, or copper, and the resulting radicals can be employed to prepare symmetrical dialkyl peroxides (Scheme 2) (see HoubenWeyl, Vol. E 13, p 341).

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