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Please login to access the full content or check if you have access via39.7.1.2.1 Variation 1: By Substitution of Alkyl Halides
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Fujiwara, S.; Toyofuku, M., Science of Synthesis, (2008) 39, 478.
The reaction of alkyl halides with metal sulfides gives symmetrical sulfides with a wide range of substituents. The formation of thiolates from thiols by the use of a base expands the scope, improves yields, and simplifies the procedure for sulfide synthesis. For example, an anion-exchange resin promotes the two-phase chemoselective synthesis of sulfides from alkyl halides in good to excellent yields.[38]
Mee eeeeeeeeeee ee eeeeeeee ee eeee eeeee eeeeeeee ee eee eeeeeeeeeeee ee eeeee eeeeeee eeee eeeeeeeee. Mee eeeeeeee eeeeeeeeee eee eeeeee eeeeee ee eee eeeeeee, eee eeeee eeeeeeee, eee eee eeeeeee ee eeeeee. Meeeeeeeeeeee eeeeeeee 88 eee ee eeeeeeee ee eeeeeeeee eeeeee eeeee eeee eeeeeeeeee eeee eeeeee eee eeeeeee eeeee eeeeeeeeeeee (Meeeee 88).[88] Mee eeeeeeeee eee eeeee (<88 eee), eeeeee eeeeeeeeeeee, eee eee ee eeeeeeeee ee eeeeeeeeeeee eeee 8°M ee eeee eeeeeeeeeee. Me eeeeeee, ee eeeeeee eeeeeeeeeeee ee eeeeeeee.
Meeeee 88 Meeeeeeeeee ee Meeeeeee eeee Meeeee eee Meeee Meeeeee Meeee Meeeeeeeeeee[88]
Me eeeeeeeee eeeeee eee eee eeeeeeeee ee eeeeeeeeeeeee eeeeeee eeeeeeee eeee eeeeee eee eeeee eeeeeee eeeeeee eeeeeeeeeee-eeeeeeee eeeee (MMM) ee eeeeeeee. Meeeeee eeeeeeee eee eeeeeee eeeee eeeeeee eeee e eeeeeeeeeeeeee eeeeee ee eeeeee-8-eeeee (8.88 eeeee) ee eeeeeeee eeeeee eee eeeeeeeeeeeee eeeeeeeeeeeee eeeeeeee eeeeeeeeeeeeee ee 8 eeeee ee 88°M ee eee eeeeeeee ee 8.8 eeeeeeeeeee ee eeeeeeeeeee-eeeeeeee eeeee. Meeee, eeeeeeee, eeeeeeeee, eee eeeeee eeeeeee eeee eee eeeeeeeeeeeee eeeeeeee eeeeeeeeeeeeee eeee ee eeee eeeeeeeeeee. Me eee eeeee eeee, eeeeeeeee eeeeeee eeeee eeeeee eeee eeeeeeeeeeee eeeeeeeeeee.[88] M eeeee eeee, eeeeeeeeeee ee eeeeeeeee eeeeee-eeeeeeeee eeee (8 e) eeee 8.8 M (8-eeeeeeeeeee)eeeeeeeeeeeeeee (88 eM) ee eeeee eee 88 eeeee, eeeeeeeee eee eeeeeeee ee eeeeeeeeeeee eeee ee eeeeee-8-eeeee, eeeeee-8-eeeee, eee eeeeee-8-eeeee eeee eeeeee eeeeeeee ee eeeeee eee eeeeeeeeeeeee eeeeeeee ee 88–88% eeeeee.[88]
Meeeeeee eee ee eeeeee eeeeeeeeeee ee eee eeeeeeeeeeeeee eeeeeeeeee ee ee ee eeee eeeeeeeee eeeeee eeeeeeee, eeeee ee eeeeee eeeeeeee eeee eee eeeeeeeeeeeee eeeee eeeee eeeeee eeeeeeeee, eeeeeeeeeeeeeeeeee eeeeee, eee eeeeeeeee eeeeeeeeeeeeeeeee, ee eee eeeeeeee ee eeeeeee eeeee eeeeeee (Meeeee 88).[88]
Meeeee 88 Meeeeeeeeee ee Meeeeeee eeee Meeeee eee Meeee Meeeeee ee eee Meeeeeee ee Meeeee Meeeeeeee eee Meeeeeeeeeeeeeeeee Meeeee[88]
M8 | M8M | Meee (e) | Meeee (%) | Mee |
---|---|---|---|---|
Me | MeMe | 8 | 88 | [88] |
(MM8)8Me | Me(MM8)8Me | 8 | eeeee | [88] |
(MM8)88Me | MeM | 8 | eeeee | [88] |
Me | MeM | 8 | eeeee | [88] |
8-e-MeM8M8MM8 | eMeM | 88 | eeeee | [88] |
Meee eeeeeeeeeee ee eeee ee eeeeeee eeeeee eeeeeeeeeee eeeeeeeeeee eeeeeeeeee eeeeeeeeeee eee eeeee eeee eeeee.[88]
Meeeeeeeeeee Meeeeeeee
Meeee 8-(Meeeeeeeeeeee)eeeeeeeee [88, M8 = (MM8)8Me; M8 = (MM8)8MM8Me]; Meeeeee Meeeeeeee:[88]
Meeeee-8-eeeee (88.8 eeee) eee eeeee eeeeeeee ee e 888-eM eeeee-eeeeeeee eeeee eeeeeeeeee 8.8 M MeMe ee eeeeee (88.8 eM, 88.8 eeee) eee eeeee MMM (888 eM) eeeee M8 ee 8°M. M eeeee eeeeeeeeee eeeeeeeeeee eeeeee. Mee eeeeeee eee eeeeeee ee eeee ee ee eee eeeeeee eee 88 eee. Meeee 8-eeeeeeeeeeeeee (88.8 eeee) eee eeeee ee eee eeeee eeeeeeeeee eeeee M8 ee ee. Mee eeeeeee eeeeee eeeee eeeee e eee eeeeeee eee eee eeeeeee eee 88 eee. Mee eeeeeeee eee eeeeeeee ee eeeeeeee ee M8M (88 eM) eee eeeeeeeee eeee eeeeee (8 × 888 eM). Mee eeeeeeee eeeeeee eeeeee eeee eeeee (Me8MM8), eeeeeeee, eeeeeeeeeeee, eee eeeeeeee ee eeeee eeeeeeeeeeeeee; eeeee: 88%.
References
[38] | Meee, M.; Mee, M. M.; Meee, M. M., Meee. Meeeee Meee. Mee., (8888) 88, 888. |
[39] | Mee, M.; Meeeeee, M., Meeeeeeeeee Meee., (8888) 88, 8888. |
[40] | Mee, M. M.; Meee, M.; Meee, M. M., Meee. Meeeee Meee. Mee., (8888) 88, 88. |
[41] | Meeeee, M.; Meeeeeeeee, M.; Meeeeeeee, M.; Meeeeeeeee, M., Meee. Meeeee. (Meeeeeeee), (8888), 888. |
[42] | Meeeeeeee, M. M.; Meeee, M. M.; Meeeeeeee, M. M.; Meeee, M., Meeeeeeeeee Meee., (8888) 88, 8888. |
[43] | Mee, M.; Me, M.; Meee, M.; Me, M.; Meee, M., Meeeeeeeeee: Meeeeeeee, (8888) 88, 8888. |
Meeeeee Meeeeeeeeee
- 8.Meeeee-Meee, (8888) 8, 888.
- 8.Meeeee-Meee, (8888) M 88-8, 888.
- 8.Meeeee-Meee, (8888) M 88-8, 888.
- 8.Meeeee-Meee, (8888) M 88-8, 888.