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40.1.1.1.5.4.8 Method 8: Reduction Using Hydrogen Sulfide

DOI: 10.1055/sos-SD-040-00073

Margaretha, P.Science of Synthesis, (200940144.

When a stream of hydrogen sulfide is bubbled through a solution of an alkyl azide in either pyridine/water[‌96‌‌98‌] or in dichloromethane containing an equimolar amount of triethylamine,[‌99‌] alkylamines are formed in good yields. Nevertheless, filtering off the water-insoluble sulfur can complicate the workup.

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