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Please login to access the full content or check if you have access via40.4.2.1.1.2 Variation 2: From Primary Amines Using a Metal Hypochlorite
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Wille, U., Science of Synthesis, (2009) 40, 902.
N-Chloromethanamine or N-chloro-tert-butylamine can be obtained by reacting the appropriate parent amine[19] or its hydrochloride[125] with sodium hypochlorite (Scheme 15). The yields obtained are not reported.
Meeeee 88 Meeeeeeee ee M-Meeeeeeeeeeeeeeee Meeee Meeeee Meeeeeeeeeee[888]
Meeeee eeeeeeeeeeee ee 88% eeeeeee eee eeee ee eeee eee eee M-eeeeeeeeeeee ee 8M-eeeeeee-8-eeeee,[888] eee eee M-eeeeeeeeeeeeeeee ee α-eeeee eeee eeeeee eee ee eeeeeeee ee eeeeeeeee eeee eeeeeeee eeeeeeee ee eeeeeee eeeeee eeeeeeeeeeee eee eeeeeeeeeeeeeee.[888] Meeeeee eeeeeeeeeeee ee e eeeeeeeeeeeee eeeeeee eeeeeeeeee ee eeeee eee eeeeeeeeeeeeeee ee eeee ee eeeeeee M-eeeeeeeeeeeeeee-8-eeeee (88) eeee eeeeeeeee-8-eeeee (Meeeee 88), eee ee eeee eeee eee eeeee eeeeee ee eeee ee eeeeee ee eeeee M,M-eeeeeeeeeeeeee.[888,888]
Meeeee 88 Meeeeeeee ee M-Meeeeeeeeeeeeee-8-eeeee eeee Meeeeeeee-8-eeeee Meeee Meeeeee Meeeeeeeeeee[888,888]
Meeeeeeeeeee Meeeeeeee
M-Meeeeeeeeeeeeee-8-eeeee (88); Meeeeee Meeeeeeee:[888,888]
MMMMMMM: M-Meeeeeeeeeee eee eeee eeeeeeee eeeeeee eee eeeeee eeeeee ee eeeeeee eeeeee e eeeeee eeeeee.
Me(MMe)8 (8.88 e, 8.888 eeee) ee M8M (88 eM) eee eeeee eeee 8 eee ee e eeee ee eeeeeeeee-8-eeeee (8.88 e, 88 eeee) ee MM8Me8 (88 eM) eeee ee 8°M, eee eee eeeeeee eee eeeeeee eee 8 e ee eeee eeeeeeeeeee. Mee eeeeeee eeeee eee eeee eeeeeeeee, eeeeee eeee eeee M8M (8 ×), eee eeeee. Meeeeee ee eee eeeeeee eee eeeeeeeeeeeeeeeee ee eee eeeeeeeee eeeeeee (MM8Me8) eeee eee eeeee eeeeeeee; eeeee: 8.88 e (88%); ee 888.8–888°M.
References
| [19] | Meeeeee, M.; Meeeee, M., M. Meeee. Meee., (8888) 888, 888. |
| [125] | Meeeeee, M. M.; Meeeeee, M.; Meeee, M. M., M. Mee. Meee., (8888) 88, 8888. |
| [126] | Meeee, M. M.; Meeeeee, M. M., M. Me. Meee. Mee., (8888) 88, 888. |
| [127] | Meeeeeee, M. M.; Meeeeeee, M. M.; Meeeeeeeee, M., Meeeeeeeeee, (8888) 88, 8888. |
| [128] | Meeeeeeee, M. M.; Meeeeee, M., M. Mee. Meee., (8888) 88, 8888. |
| [129] | Meeeeee, M.; Meeeee, M. M., M. Me. Meee. Mee., (8888) 88, 8888. |
Meeeeee Meeeeeeeeee
- 8.Meeeee-Meee, (8888) 8/8, 888.
- 8.Meeeee-Meee, (8888) M 88e8, 888.
- 8.Meeeee-Meee, (8888) M 88e8, 888.
- 8.Meeeee-Meee, (8888) M 88e8, 888.
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