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Please login to access the full content or check if you have access via Method 5: Ammoniumimines by Deprotonation of Hydrazinium Compounds

DOI: 10.1055/sos-SD-040-00813

Rademacher, P.Science of Synthesis, (2009401198.

Deprotonation of 1,1,1-trialkylhydrazinium salts 224 can be achieved in small quantities with strong bases (Scheme 105).[‌254‌] All operations have to be carried out in an inert atmosphere, e.g. of pure dinitrogen. Special precautions are necessary when the (1,1,1-trialkylammonium)imines 225 are isolated.[‌254‌] At 20°C they decompose in a few hours.

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