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40.9 Product Class 9: Triazanes and Tetrazanes

DOI: 10.1055/sos-SD-040-00937

Schaumann, E.Science of Synthesis, (2009401253.

General Introduction

The first triazane derivative was reported as early as 1900 when N-nitroso hydrazide 1 was reduced to give triazane 2, which was trapped as the benzylidene derivative 3 (Scheme 1).[‌1‌] This structure assignment was later confirmed.[‌2‌]

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