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Please login to access the full content or check if you have access via Method 1: Synthesis via Reaction of Anilines with Disulfur Dichloride

DOI: 10.1055/sos-SD-040-00963

Chemler, S. R.Science of Synthesis, (2009401278.

2,4-Di-tert-butyl-6-methyl-N-thiosulfinylaniline (27) has been synthesized in very good yield by condensation of 2,4-di-tert-butyl-6-methylaniline (26) with sulfur monochloride (Scheme 14).[‌55‌] However, the reaction is not general, and other anilines either do not provide the N-thiosulfinylarylamines or provide them in low yields along with other compounds.

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