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Please login to access the full content or check if you have access via Method 1: Synthesis of N,N′-Bis(methoxycarbonyl)sulfur Diimide

DOI: 10.1055/sos-SD-040-00963

Chemler, S. R.Science of Synthesis, (2009401279.

N,N-Bis(methoxycarbonyl)sulfur diimide (29) has been used frequently in organic synthesis (see Section This reagent has been prepared by treatment of methyl N,N-dichlorocarbamate (28)[‌17‌,‌62‌] with sulfur dichloride in the presence of pyridine (Scheme 15).[‌16‌] More recently, it has been prepared by disproportionation of methyl N-sulfinylcarbamate in the presence of pyridine.[‌18‌]

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